Activity 7: Acids and Bases

Activity 7: Acids and Bases

Water is everywhere! So, lets spend one more activity learning about one of the key aspects of water. Water has the ability to dissociate (break apart from HOH (or H₂O) into H+ ions and OH- ions). We refer to solutions with lots of H+ ions as acids and solutions with lots of OH- ions as bases. By adding chemicals with H+ ions acidic solutions can be made. By adding chemicals with OH- ions basic solutions can be made.

• Teaching Idea “Concept Questions for Chemistry using PhET” posted by Trish Loeblein on the pH Scale simulation at PHET (http://phet.colorado.edu/en/simulation/ph-scale).

1. F, pH levels identify a solution
2. D, pH levels need to be above 7 to be considered a basic solution
3. C, because the solution is more acidic
4. B, due to higher levels of OH-
5. D, three of them have more acidic levels
6. A, more H20 increases the level
7. B, decrease the pH
8. A
9. E
10. A, Since the pH is not 7, then something was added to make the equilibrium shift left. For example, if NaOH was added to water, OH
- is immediately in the solution and some of it will react with the H3O+ , so the pH (which is inversely related to [H3O+ ]), goes up. If something like HCl were added there would be more H3O+ , which would also cause a shift left, but there would be less OH- , (which is directly related to pH), so the pH is less than 7.

• Teaching Idea “Intro to Strong and Weak Acids and Bases” posted by Chris Bires on the Acid-Base Solutions simulation (http://phet.colorado.edu/en/simulation/acid-base-solutions)

Name: Visualizethis39/penaj

Introduction to Strong and Weak Acids and Bases PhET Lab (rvsd 5/2011)

        How does the strength of an acid or base affect conductivity?pH?

Introduction:

When you test your pool’s pH, what are you those little vials or paper strips telling you?  When you hear an acid called “strong” or “weak”, what do those terms refer to?  In aqueous solutions, compounds can exist as molecules (undissociated) or ions (dissociated).  When an acid or a base exists in solution nearly completely as dissociated ions, we refer to that acid or base as strong.  A weak acid or base will donate ions to the solution, but will remain primarily as undissociated molecules.

Notation:

Acids are abbreviated HA, with the H representing the proton (H+) the acid donates to the solution.  The A is referred to as the acidic anion (A-) that is left in solution as the proton is donated.

Strong Bases are abbreviated MOH, with the OH representing the hydroxide ion (OH-) the base donates to the solution.  The M is cation (M+) that is left in solution as the hydroxide is donated. .

Autoionization:

Even without any acid or base added a very small number of water molecules will form protons (H+) and hydroxide ions (OH-).  The protons will then form hydronium ions, the acid ion.

Procedure: PhET Simulations à Play With Sims à Chemistryà Acid-Base Solutions à  

The concentration of the acids and bases used in the  at 0.010 (10^-2) Molar.

·         Begin with a strong acid and lower the pH probe into the beaker.  What is the pH of this solution? 

·         Test this strong acid with both pH paper and the conductivity probe.  What color does the pH indicator become?  Is this strong acid an electrolyte?  Does current travel through this solution?

·         Repeat the above tests with the weak acid, the strong base, and the weak base, and water.  Collect your observations in the table below:

	Strong Acid	Weak Acid	Strong Base	Weak Base	Water
pH meter read (value)
pH paper (color)
Conductivity (bright/dim/none)
Exists as Mostly (ions/molecules)

Procedure:

This simulation allows you to change the concentration of a strong and weak acid and base.

Complete the table below for some strong acids and bases and weak acids and bases by adjusting the concentration.

Strong Acids

Strength	Initial Acid Concentration (mol/L)	[HA] (mol/L)	[A-] (mol/L)	[H+] (mol/L)	pH
	.010 M
	.050 M
	.100 M
	1.00 M

Weak Acids

Strength (approximately)	Initial Acid Concentration (mol/L)	[HA] (mol/L)	[A-] (mol/L)	[H+] (mol/L)	pH
	.015 M
	.150 M
	.015 M
	.150 M

Strong Bases

Strength	Initial Acid Concentration (mol/L)	[MOH] (mol/L)	[M+] (mol/L)	[OH-] (mol/L)	pH
	.010 M
	.050 M
	.100 M
	1.00 M

Weak Bases

Strength (approximately)	Initial Acid Concentration (mol/L)	[B] (mol/L)	[BH+] (mol/L)	[OH-] (mol/L)	pH
	.015 M
	.150 M
	.015 M
	.150 M

Conclusion Questions:

1.      A strong acid is very concentrated / exists primarily as ions. (circle)

2.      A weak base is a nonelectrolyte / weak electrolyte / strong electrolyte.

3.      A strong base is a nonelectrolyte / weak electrolyte / strong electrolyte.

4.      At the same concentration (Molarity) a strong acid will have a higher / lower / the same pH as a weak acid.

5.      As concentration of a weak acid increases, the pH increases / decreases / remains constant.

6.      As concentration of a weak base increases, the pH increases / decreases / remains constant.

7.      As the concentration of a weak acid increases, the number of ions increases / decreases / remains constant.

8.      As the concentration of a weak acid increases, conductivity increases / decreases / remains constant.

9.      As the strength of a weak acid increases, the proportion of ions to molecules increases / decreases.

10.  As the strength of a weak acid increases, the conductivity increases / decreases / remains constant.

11.  What are the pH values of a weak acid with a concentration of 0.10 and a strong acid with a concentration of 0.01, ten times lower?     Weak acid, 0.10 M :____________    Strong Acid, 0.01 M :____________

Explain the significance of the results of your calculation above. ____________________________